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DESORPTION OF RARE EARTH IONS FROM ETHYLENEDIAMINETETRAACETATE-INTERCALATED Cu-AL LAYERED DOUBLE HYDROXIDE USING
Pages : [61] - [69]
Received : February 04, 2013
Communicated by : Professor Jifan Hu
Abstract
It is found that rare earth ions combined with ethylenediaminetetraacetate (edta) ions in the interlayers of loaded (Cu-Al layered double hydroxides intercalated with edta ions) can be exchanged with in aqueous solution. The level of recovery decreases in the order of for all time durations. The difference between the recovery levels can be attributed to the difference between the stabilities of the corresponding chelate complexes. The chelate formation constant for is much larger than those for and indicating that is effective for the recovery of and Thermodynamically, it is difficult for the to exchange with the combined with edta ions in the interlayers of because the chelate formation constant for is close to that for
Keywords
desorption, rare earth, EDTA, layered double hydroxide.